应天平

简介


应天平,男,特聘研究员,博士生导师。2010年至2015年就读中国科学院物理研究所,获博士学位。2015年至2018年在复旦大学任希德博士后,2018年至2021年在日本东京工业大学从事博士后研究(Hideo Hosono研究组),2021年6月加入中国科学院物理研究所,入选中科院 "引进国外杰出人才(I类)"。主持项目包括:中科院人才项目、面上项目、科技部重点研发子课题等。

课题组网页:a02.iphy.ac.cn

主要研究方向


 

1. 新超导体发现。

2. 新功能材料和新奇物性探索。

过去的主要工作及获得的成果


本人长期从事新功能材料的结构设计与晶体生长,并基于新发现的材料体系开展多自由度物性调控。以第一作者或通讯作者身份发表Nat. Chem.、 PRL(2)、JACS(6)、Sci. Adv.、Nat. Commun.、Sci. Bull.(2)、Adv. Mater.(4)、Angew. Chem. Int. Ed.、Adv. Sci. (2) 等,代表性工作有:

1. 新超导体发现及调控:

› 提出低温途径制备新型铁基超导体,解决插层铁硒超导体系相分离难题 [Sci. Rep. 2(1), 1 (2012)];

› 发现铁硒基超导体中分立超导相 [JACS 135(8), 2951 (2013)];

› 利用固态离子栅压调控技术,澄清铁硒基超导相图的争议 [PRL 121(20), 207003 (2018)];

› 以“空位序”为母体的超导体Ir16Sb18 [Sci. Bull. 66(4), 327 (2021)];

› 利用维度调控和选择性氧化,实现CsV3Sb5的空穴掺杂 [PRL 127(23), 237001 (2021)];

› 空穴掺杂方钴矿超导体X@Ir4X12(X=P, As) [JACS 144(14), 6208 (2022)];

› 发现“超原子”体系Au6Te12Se8对压力的独特响应行为 [JACS 144, 45, 20915 (2022)];

› 将CsV3Sb5解理至二维极限,发现其CDW机理存在电声耦合到电子关联的转变 [Nat. Commun. 14, 2492 (2023)];

› SnAs体系中压力诱导新超导基元 [Angew. Chem. Int. Ed. 62, e2022160 (2023)];

› 发现系列(RO)nPb (R = 稀土元素, n = 1,2)类单层铅化合物及其超导电性 [JACS, 145, 31, 17435 (2023)];

› 发现压力导致一种罕见的晶体-非晶-晶体相变,且超导Tc在非晶区提升[Adv. Mater. 36, 2401118 (2024)].

2. 其他功能晶体探索:

› Anderson绝缘体单晶LixFe7Se8 [Sci. Adv. 2(2), e1501283 (2016)];

› “高熵二维材料”新体系 [JACS 143(18), 7042 (2021); 综述:Adv. Sci. 2203219 (2022)];

› [(CH3)3(CH2CH2Cl)N]2InCl5•H2O 一种潜在的忆容器候选材料 [JACS 146(1), 281-288 (2024)];

› 氢键控制107数量级的金属绝缘体转变,突破氢键不易影响电输运性质的传统认识 [Nat. Chem. (2024)];

› 高熵二维材料在电催化方面的应用 [Adv. Mater. 2404772 (2024).

代表性论文及专利


†一作*通讯(含共同)文章:

【BOOK】

1. T.X. Yu, T. P. Ying*, High-Entropy Alloy Superconductors, Chapter 9: High Entropy van der Waals Superconductors, Springer, DOI : 10.1007/978-981-97-4129-8

【Article】

29. J.J. Wang, X. Liu, L. Zhang, J.-G. Guo*, T.P. Ying* "Influence of dimensionality on superconductivity in pressurized 3D SnPSe3 single crystal" Phys. Rev. Materials 8, 074803 (2024)

28. H. Liu, T.X. Yu, Z.H. Zhang*, T.P. Ying*, CPL 41, 077401 (2024).

27. Z.K. Xie†, R. Ruo†, T. P. Ying†*, Y. R. Gao†*, J.-G. Guo*, X.L. Chen*, et al. "Dynamic-to-static switch of hydrogen bonds induces a metal-insulator transition in an organic-inorganic superlattice" Nat. Chem. (2024) doi.org/10.1038/s41557-024-01566-1 氢键一般被认为不能有效改变物质的电学输运性质,我们利用氢键的动力学到静态转变实现高达7个数量级的金属绝缘体转变,为设计未来新型电子学器件提供新思路。

26. N. Sun†, Z.C. Zheng†, Z.Z. Lai†, T. P. Ying*, H. F. Wang*M. Lei*, K. Huang*. et al.  "Augmented Electrochemical Oxygen Evolution by d-p Orbital Electron Coupling" Adv. Mater. 2404772 (2024).

25. Y. Zhao†, T. P. Ying†*, C. Z. Chen*, Y. P. Qi*, et al. "Disorder-Broadened Phase Boundary with Enhanced Amorphous Superconductivity in Pressurized In2Te5" Adv. Mater. 36, 2401118 (2024), 发现一种罕见的压力诱导CAC相变,且超导Tc在非晶区提升,可能与无序诱导的波函数分形有关。

24. M. Z. Yang, T. P. Ying*, J.-G. Guo*, "Stereochemical Rearrangement of Functional Units in Pressurized Sn4As3 Superconductor" Chem. Mater.  36, 7, 3120–3127 (2024).

23. J. L. Lu, T. P. Ying*, Y. R. Gao*, S. F. Jin*, X. L. Chen*, et al. "High, multiple and non-volatile polarizations in organic-inorganic hybrid [(CH3)3(CH2CH2Cl)N]2InCl5•H2O for memcapacitor" J. Am. Chem. Soc. 146 (1), 281-288 (2024) 一种具有大极化的潜在忆容器材料

22. 刘旭,应天平* 亚稳态新型铁硒基超导体探索 《中国科学: 物理学 力学 天文学》邀请综述 Sci Sin-Phys Mech Astron, 53: 127406 (2023)

21. X. Chen†, J. Deng†, S.-F. Jin†, T. P. Ying*, S. X. Du*, J.-G. Guo*, X. L. Chen*, et al. "Two-dimensional Pb square nets from bulk (RO)nPb (R = rare earth metals, n = 1,2)" J. Am. Chem. Soc., 145, 31, 17435–17442 (2023). 发现类单层Pb电子结构的一系列化合物及其超导电性

20. B. Q. Song†, T. P. Ying†*, X. X. Wu†, W. Xia†, Q. W. Yin†, H. C. Lei*, Y. F. Guo*, S. Y. Li*, et al. "Anomalous enhancement of charge density wave in kagome superconductor CsV3Sb5 approaching the 2D limit" Nat. Commun. 14, 2492 (2023). 发现笼目CsV3Sb5的CDW在25层可能发生从电声耦合(高温)到电子关联(低温)的变化。

19. J. J. Wang†, T. P. Ying†*, J. Deng†, C. Y. Pei†, Y. P. Qi*, J.-G. Guo*, et al. "Superconductivity in an Orbital-reoriented SnAs Square Lattice: a Case Study of Li0.6Sn2As2 and NaSnAs" Angew. Chem. Int. Ed. 62, e2022160 (2023). 高压诱导SnAs3-SnAs4结构拓扑相变,实现SnAs四方平面超导基元

18. X. Chen†, J. J. Wang†, T. P. Ying*, J.-G. Guo*, X. L. Chen*, et al. "Insulator-metal-Superconductor transition in medium-entropy van der Waals compound MPSe3 (M=Fe, Mn, Cd, and In) under high pressures" Phys. Rev. B 106, 184502 (2022).

17. X. Chen, T. P. Ying*, J.-G. Guo*, X. L. Chen*, et al. "Superatomic-charge-density-wave in cluster-assembled Au6Te12Se8 superconductor" J. Am. Chem. Soc., 144, 45, 20915–20922 (2022). “超原子”超导体。

16. Z. X. Chen, Y. X. Yang, J. Deng, S. X. Du, T. P. Ying*, J.-G. Guo*, X. L. Chen, "Delicate Superconductivity in Nodal-line NaAlGe Single Crystal" J. Phys. Condens. Matter, J. Phys.: Condens. Matter 34 495702 (2022)

15. T. P. Ying†, T. X. Yu†, Y. P. Qi, X. L. Chen*, H. Hosono*, "High entropy van der Waals materials" Adv. Sci. 2203219 (2022)  高熵二维材料综述

14. J.-G. Guo†, T. P. Ying†, Q. Zheng*, X. L. Chen*, et al. "Surface microstructures of lunar soil returned by Chang’e-5 mission reveal an intermediate stage in space weathering process"  Science Bulletin, 67(16) 1696-1701 (2022)

13. C. Y. Pei, T. P. Ying*, Y. P. Qi*, et al. "Pressure-induced reemergence of superconductivity in BaIr2Ge7 and Ba3Ir4Ge16 with cage structures" Matter and Radiation at Extremes 7, 038404 (2022)

12. C. Y. Pei†, T. P. Ying*,†, Q. H. Zhang†, H. Hosono*, Y. P. Qi*, et al. "Caging-pnictogen-induced superconductivity in skutterudites IrX3 (X = As, P)" J. Am. Chem. Soc. 144, 14, 6208-6214 (2022) 首个空穴型方钴矿超导体

11. Y. X. Yang, T. P. Ying*, J.-G. Guo*, X. L. Chen*, et al. "Discovery of two families of VSb-based compounds with V-kagome lattice" Chin. Phys. Lett. 38, 127102 (2021) (编辑推荐)

10. Y. P. Qi*†, T. P. Ying*†, H. Hosono*, et al. “Superconductivity from buckled-honeycomb-vacancy ordering” Science Bulletin, 66(4), 327-331 (2021) (封面文章) 

9. Y. P. Song†, T. P. Ying†, X. X. Wu*,J.-G. Guo*, X. L. Chen*, et al. “Competition of superconductivity and charge density wave in selective oxidized CsV3Sb5 thin flakes” Phys. Rev. Lett. 127, 237001 (2021) 

8. T. P. Ying*, T. X. Yu, Y.-S. Shiah, C. H. Li, J. Li, Y. P. Qi*, H. Hosono*, “High-Entropy van der Waals Materials Formed from Mixed Metal Dichalcogenides, Halides, and Phosphorus Trisulfides” J. Am. Chem. Soc. 143, 7042-7049 (2021) 高熵二维材料。

7. T. P. Ying, H. Hosono*, et al. “Anomalous charge state evolution and its control of superconductivity in M3Al2C (M= Mo, W)” iScience, 101196 (2020)

6. T. P. Ying, Y. P. Qi, H. Hosono*, “Superconductivity with strong electron-phonon coupling in noncentrosymmetric W3Al2C” Phys. Rev. B 100 (9), 094522 (2019)

5. T. P. Ying†, M. X. Wang†, S. Y. Li*, et al. “Discrete superconducting phases in FeSe-derived superconductors” Phys. Rev. Lett. 121, 207003 (2018)

4. T. P. Ying, Y. Q. Gu, X. Chen, X. B. Wang, S. F. Jin, L. L. Zhao, W. Zhang, X. L. Chen*, “Anderson localization of electrons in single crystals: LixFe7Se8”, Sci. Adv. 2, e1501283 (2016) Anderson局域化

3. T. P. Ying, S. Y. Li*, et al. “Nodal superconductivity in FeS: Evidence from quasiparticle heat transport”, Phys. Rev. B, 94, 100504(R) (2016)

2. T. P. Ying, X. L. Chen*, G. Wang*, et al. “Superconducting Phases in Potassium-Intercalated Iron Selenides”, J. Am. Chem. Soc. 135, 2951-2954 (2013) JACS高被引论文。

1. T. P. Ying, X. L. Chen*, G. Wang*, et al. “Observation of superconductivity at 30~46K in AxFe2Se2 (A=Li, Na, Ba, Sr, Ca, Yb, and Eu)”, Sci. Rep. 2, 426 (2012) 率先提出制备高温超导体的全新途径,成为铁基超导制备的主流方法之一。高被引论文。

 

部分合作文章:

4. X. Chen, Y. Jiang, H. Xiong, T. Ying, G. Tian, and F. Wei, "Ultrasmall single-layered NbSe2 nanotubes flattened within a chemical-driven self-pressurized carbon nanotube", Nat. Commun. accepted (2023)

3. R. Sun, J. Deng, X. Wu, M. Hao, K. Ma, Y. Ma, C. Zhao, D. Meng, X. Ji, Y. Ding, Y. Pang, X. Qian, R. Yang, G. Li, Z. Li, L. Dai, T. Ying, H. Zhao, S. Du, G. Li, S. Jin, X. Chen, "High anisotropy in electrical and thermal conductivity through the design of aerogel-like superlattice (NaOH)0.5NbSe2", Nat. Commun. 14(1), 6689 (2023)

2. S..J. Tian, J.F. Zhang, C Li, T. P. Ying, S. Y. Li, X. Zhang, K. Liu, H. C. Lei*, "Ferromagnetic van der Waals Crystal VI3", J. Am. Chem. Soc. 141(13), 5326-5333 (2019)

1. R. J. Sun, S. F. Jin, L. Gu, Q. Zhang, Q. Huang, T. Ying, Y. Peng, J. Deng, Z. Yin, X. Chen, "Intercalating Anions between Terminated Anion Layers: Unusual Ionic S–Se Bonds and Hole-Doping Induced Superconductivity in S0.24(NH3)0.26Fe2Se2", J. Am. Chem. Soc. 141 (35), 13849-13857 (2019)

 

Google Scholar:

https://scholar.google.com/citations?user=DKfufdcAAAAJ&hl=zh-CN

目前的研究课题及展望


1. 高温超导和新功能材料探索;

2. 多自由度物态调控。

承担课题:

1. 科技部国家重点研发计划(2021-2026)课题负责人

2. 基金委面上项目(2023-2026)负责人

3. 中科院人才项目 (2023)负责人

4. 基金委原创探索项目(2023-2025)参与

培养研究生情况


在站博士后1人,联培4人。每年拟招收研究生1-2名或空缺,对自主性要求较高,欢迎对超导、晶体和新材料感兴趣的同学咨询联系。

协助郭建刚研究员指导博士后宋艳鹏,发表PRL (2021);

协助陈小龙研究员指导博士后陈旭,发表JACS (2022);JACS (2023);

协助郭建刚研究员指导博士生王俊杰,发表Angew. Chem. Int. Ed. (2023);

协助复旦李世燕教授指导博士生宋伯钦(现为课题组博士后,获聘中国科学院特别研究助理),发表Nat. Commun. (2023);

协助陈小龙研究员指导博士生路佳丽,发表JACS (2024);

协助上科大齐彦鹏教授指导博士生赵毅,发表Adv. Mater. (2024);

协助陈小龙研究员指导博士生谢圳楷,发表Nat. Chem. (2024)。

其他联系方式


办公室:物理所M楼1012室

 

电话


010-82649905

Email


ying@iphy.ac.cn

Baidu
map